T. Kamperidis, A. Tremouli, Antonis Peppas, G. Lyberatos
First MFC model coupling Butler-Volmer kinetics to substrate mass balance. Maximum power density 2.4 W/m² at optimal conditions; cell voltage drops from 0.77 V (open-circuit) to 0.10 V under load. Acetate concentration and flow rate dominate sensitivity. Validated against ~30-day experimental runs.
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Bioelectrochemical systems have been the focus of extensive research due to their unique advantages of converting the chemical energy stored in waste to electricity. To acquire a better understanding and optimize these systems, modelling has been employed. A 2D microbial fuel cell (MFC) model was developed using the finite element software Comsol Multiphysics® (version 5.2), simulating a two-chamber MFC operating in batch mode. By solving mass and charge balance equations along with Monod–Butler–Volmer kinetics, the operation of the MFC was simulated. The model accurately describes voltage output and substrate consumption in the MFC. The computational results were compared with experimental data, thus validating the model. The voltage output and substrate consumption originating from the model were in agreement with the experimental data for two different cases (100 Ω, 1000 Ω external resistances). A polarization curve was extracted from the model by shifting the external resistance gradually, calculating a similar maximum power (47 mW/m2) to the observed experimental one (49 mW/m2). The validated model was used to predict the MFC response to varying initial substrate concentrations (0.125–4 g COD/L) and electrolyte conductivity (0.04–100 S/m) in order to determine the optimum operating conditions.